Create a new PST/ MAP a PST file in Outlook 2010

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Steps:

1.  Click on File- > Account Settings icon -> Account settings option 

2.  Once the Account Settings option is clicked, the following window would open up as shown below.

By default the EMAIL tab would be chosen. Now to create a new PST file, choose the tab DATA FILES as shown and follow the below given steps.

1.  Click on ADD

2.  Choose the location, where the PST file has to be saved and then enter the NAME of the file and click on OK

3.  Now the PST file would be created in the desired location.

4.  For mapping an PST that’s missing from outlook, follow the same steps as mentioned above.